• 文献标题:   High performance nitrogen-doped porous graphene/carbon frameworks for supercapacitors
  • 文献类型:   Article
  • 作  者:   NING XT, ZHONG WB, LI SC, WANG YX, YANG WT
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY A
  • ISSN:   2050-7488 EI 2050-7496
  • 通讯作者地址:   Hunan Univ
  • 被引频次:   67
  • DOI:   10.1039/c4ta01038h
  • 出版年:   2014

▎ 摘  要

Nitrogen-doped porous graphene/carbon (NPGC) framework electrode materials have been synthesized via chemical activation of graphene oxide/polypyrrole (GOP) composites with KOH. The effects of the mass ratio of KOH/GOP and activation temperature on the electrochemical performance of NPGC have been discussed. It is found that the NPGC prepared by activating GOP (GO : Py = 1 : 40) with 3.5 times mass of KOH at 650 degrees C (NPGC650) exhibits the highest specific capacitance of 405 F g(-1) at a current density of 0.2 A g(-1). Particularly, the specific capacitance still remains at 249 F g(-1) even at a current density as high as 10 A g(-1). Moreover, 96% of the capacitance can be retained after 1000 cycles even under a high operation current of 10 A g(-1). The present work provides a novel strategy to synthesize NGPC electrode material for supercapacitors.