• 文献标题:   One-step synthesis of TiC/multilayer graphene composite by thermal plasma
  • 文献类型:   Article
  • 作  者:   KIM DW, HEO US, KIM KS, PARK DW
  • 作者关键词:   thermal plasma, graphene, tic, tic/multilayer graphene composite, onestep synthesi
  • 出版物名称:   CURRENT APPLIED PHYSICS
  • ISSN:   1567-1739 EI 1878-1675
  • 通讯作者地址:   Inha Univ
  • 被引频次:   2
  • DOI:   10.1016/j.cap.2018.02.006
  • 出版年:   2018

▎ 摘  要

Graphene hybrid materials have been attracting a great deal of attention due to their superior properties. Nevertheless, problems such as expensive and complicated production processes have limited their application to industrial fields. Here, we introduce a one-step synthesis of titanium carbide (TiC) nanoparticles on multilayer graphene nanosheet (TiC/multilayer graphene) composites using thermal plasma. Although there are three types of titanium alkoxides (titanium ethoxide, titanium isopropoxide and titanium n-butoxide), the TiC/multilayer graphene was synthesized from only titanium isopropoxide. The injection temperature of the precursor was varied to investigate the effects of the precursor concentration in the plasma region. A TiC/multilayer graphene hybrid material with crystalline TiC nanoparticles below 50 nm on graphene nanosheets was observed. The number of graphene nanosheet layers varied from one to over 10 according to the injection temperature. When titanium ethoxide and titanium butoxide were injected, TiC with amorphous carbon and graphite were synthesized. The formation of graphene is considered to be affected by the structure of the carbon chain in the precursors and the concentration in the plasma region. (C) 2018 Elsevier B.V. All rights reserved.