• 文献标题:   In-situ plantation of Fe3O4@C nanoparticles on reduced graphene oxide nanosheet as high-performance anode for lithium/sodium-ion batteries
  • 文献类型:   Article
  • 作  者:   XU JL, ZHANG X, MIAO YX, WEN MX, YAN WJ, LU P, WANG ZR, SUN Q
  • 作者关键词:   anode, fe3o4, lithium/sodiumion battery, nanosheet, reduced graphene oxide
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:  
  • 被引频次:   46
  • DOI:   10.1016/j.apsusc.2021.149163 EA FEB 2021
  • 出版年:   2021

▎ 摘  要

Fe3O4 is considered to be an ideal substitute for graphite anode due to its high lithium (Li) and sodium (Na) storage capacity, however, its sharp volume change after lithiation/sodiumization and poor electrical conductivity have brought huge challenges to the practical application. In this study, a lamellar Fe3O4-based electrode was constructed via an in-situ plantation of carbon-coated Fe3O4 nanoparticles on the surface of the reduced graphene oxide nanosheet. Owing to the ultra-small carbon-coated Fe3O4 nanoparticles (similar to 12.5 nm) and unique two-dimensional lamellar structure, the obtained sample displays excellent cycle and rate performance in lithium/sodium-ion batteries. A high reversible capacity of 849 mA h g(-1) is obtained at 500 mA g(-1) after 120 cycles for lithium-ion batteries and a discharge capacity up to 429 mA h g(-1) is remained at 100 mA g(-1) after 300 cycles for sodium-ion batteries.