• 文献标题:   Decavanadate-graphene oxide nanocomposite as an electrode material for electrochemical capacitor
  • 文献类型:   Article
  • 作  者:   MAITY S, DAS PP, MAL SS
  • 作者关键词:   sodium decavanadate, graphene oxide, nanocomposite, supercapacitor, cyclic voltammogram
  • 出版物名称:   MATERIALS TECHNOLOGY
  • ISSN:   1066-7857 EI 1753-5557
  • 通讯作者地址:  
  • 被引频次:   8
  • DOI:   10.1080/10667857.2021.1924439 EA MAY 2021
  • 出版年:   2022

▎ 摘  要

We have synthesized new electrode material for the supercapacitor application. Polyoxovanadates (POVs) have been used for energy storage electrode materials due to their fast multi-electron redox properties. The formation of SDV/GO composites was confirmed using various analytical methods, e.g., Fourier transforms infrared spectroscopy (FTIR) and powder X-ray diffraction (XRD), followed by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The composite electrode's electrochemical behavior was studied using a neutral 1 M sodium sulphate (Na2SO4) solution in three-electrode cyclic voltammetry (CV) system. The SDV/GO composite electrode showed a specific capacitance of 306 F/g for a scan rate of 5 mV/s and a corresponding energy density of 42.4 Wh/Kg. Galvanostatic charge/discharge exhibits a specific capacitance of 310 F/g with energy densities of 43.08 Wh/kg. Electrochemical impedance spectroscopy (EIS), which was used to investigate interface property, yielded a considerably higher power density of 172.41 KW/kg with an equivalent series resistance of 5 ohm.