• 文献标题:   Synthesis of sulfonated graphene/carbon nanotubes/manganese dioxide composite with high electrochemical properties
  • 文献类型:   Article
  • 作  者:   LI W, XU HZ, CUI MJ, ZHAO J, LIU FQ, LIU TF
  • 作者关键词:   mno2, electrical conductivity, sulfonated graphene sg, supercapacitor
  • 出版物名称:   IONICS
  • ISSN:   0947-7047 EI 1862-0760
  • 通讯作者地址:   Qingdao Univ Sci Technol
  • 被引频次:   4
  • DOI:   10.1007/s11581-018-2767-0
  • 出版年:   2019

▎ 摘  要

Combining MnO2 with conductive carbon materials is an efficient approach to improve the electrical conductivity of MnO2-based electrodes, which could greatly improve the electrochemical performance of supercapacitors. Here, a ternary composite consisting of sulfonated graphene, carbon nanotubes, and manganese dioxide (SG/CNTs/MnO2) has been successfully fabricated by a facile yet efficient method. The electrochemical properties are evaluated by cyclic voltammetry (CV), galvanostatic charge/discharge (GCD), and electrochemical impedance spectroscopy (EIS) techniques. The results show a prominent improvement of electrochemical performance of MnO2-based electrodes. For instance, the specific capacitance of SG/CNTs/MnO2 composite is 336.4Fg(-1) at the current density of 0.5Ag(-1), which is much higher than pure MnO2 (77.1Fg(-1)) and binary SG/MnO2 (213.0Fg(-1)). Moreover, SG/CNTs/MnO2 composite shows good cycling stability with 91.3% capacitance retention after 10,000cycles at a current density of 5Ag(-1).