• 文献标题:   FeNb2O6/reduced graphene oxide composites with intercalation pseudo-capacitance enabling ultrahigh energy density for lithium-ion capacitors
  • 文献类型:   Article
  • 作  者:   KONG SY, ZHANG X, JIN BB, GUO XG, ZHANG GQ, HUANG HS, XIANG XZ, CHENG K
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:  
  • 通讯作者地址:  
  • 被引频次:   1
  • DOI:   10.1039/d1ra03198h
  • 出版年:   2021

▎ 摘  要

Lithium-ion capacitors (LICs), which combine the characteristics of lithium-ion batteries and supercapacitors, have been well studied recently. Extensive efforts are devoted to developing fast Li+ insertion/deintercalation anode materials to overcome the discrepancy in kinetics between battery-type anodes and capacitive cathodes. Herein, we design a FeNb2O6/reduced graphene oxide (FNO/rGO) hybrid material as a fast-charge anode that provides a solution to the aforementioned issue. The synergetic combination of FeNb2O6, whose unique structure promotes fast electron transport, and highly conductive graphene shortens the Li+ diffusion pathways and enhances structural stability, leading to excellent electrochemical performance of the FNO/rGO anode, including a high capacity (770 mA h g(-1) at 0.05 A g(-1)) and long cycle stability (95.3% capacitance retention after 500 cycles). Furthermore, the FNO/rGO//ACs LIC achieves an ultrahigh energy density of 135.6 W h kg(-1) (at 2000 W kg(-1)) with a wide working potential window from 0.01 to 4 V and remarkable cycling performance (88.5% capacity retention after 5000 cycles at 2 A g(-1)).