• 文献标题:   Polyoxomolybdate-Polypyrrole-Graphene Oxide Nanohybrid Electrode for High-Power Symmetric Supercapacitors
  • 文献类型:   Article
  • 作  者:   MAITY S, MADHUSREE JE, BIRADAR BR, CHANDEWAR PR, SHEE D, DAS PP, MAL SS
  • 作者关键词:  
  • 出版物名称:   ENERGY FUELS
  • ISSN:   0887-0624 EI 1520-5029
  • 通讯作者地址:  
  • 被引频次:   5
  • DOI:   10.1021/acs.energyfuels.1c03300 EA NOV 2021
  • 出版年:   2021

▎ 摘  要

Supercapacitors have emerged as one of the most promising candidates for high-performance, safe, clean, and economical routes to store and release of nonfossil energy. Designing hybrid materials by integrating double-layer and pseudocapacitive materials is crucial to achieving high-power and high-energy storage devices simultaneously. Herein, we synthesized a polyoxomolybdate-polypyrrole-graphene oxide nanohybrid via a one-pot reaction. The inclusion of polypyrrole enables a uniform distribution of the polyoxomolybdate clusters; it also confines the restacking of graphene oxide nanosheets. The structural and morphological analysis to unveil the nanohybrid architecture implies excellent interfacial contact, enabling fast redox reaction of polyanions, and a quick transfer of charge to the interfaces. Electrochemical characteristics tested under a two-electrode system exhibit the highest capacitance of 354 F g(-1) with significantly high specific energy and power of 49.16 Wh kg(-1) and 999.86 W kg(-1), respectively. In addition, the cell possesses a high-rate capability and long cycle life by maintaining 96% of its capacitance over 5000 sweeping cycles. The highest specific power of similar to 10 000 W kg(-1) was computed with Coulombic efficiency of 92.30% at 5 A g(-1) current density. Electrochemical impedance spectroscopy additionally reveals enhanced redox charge transfer due to double hybridization. Furthermore, it also demonstrates the impedance and capacitive behavior of supercapacitor cells over a definite frequency regime.