• 文献标题:   Effect of Pt nanoparticle decoration on the H-2 storage performance of plasma-derived nanoporous graphene
  • 文献类型:   Article
  • 作  者:   KOSTOGLOU N, LIAO CW, WANG CY, KONDO JN, TAMPAXIS C, STERIOTIS T, GIANNAKOPOULOS K, KONTOS AG, HINDER S, BAKER M, BOUSSER E, MATTHEWS A, REBHOLZ C, MITTERER C
  • 作者关键词:   nanoporous graphene, plasma treatment, pt nanoparticle, nanocomposite, metal decoration, hydrogen storage
  • 出版物名称:   CARBON
  • ISSN:   0008-6223 EI 1873-3891
  • 通讯作者地址:  
  • 被引频次:   11
  • DOI:   10.1016/j.carbon.2020.08.061
  • 出版年:   2021

▎ 摘  要

A nanoporous and large surface area (similar to 800 m(2)/g) graphene-based material was produced by plasma treatment of natural flake graphite and was subsequently surface decorated with platinum (Pt) nanosized particles via thermal reduction of a Pt precursor (chloroplatinic acid). The carbon-metal nanocomposite showed a similar to 2 wt% loading of well-dispersed Pt nanoparticles (<2 nm) across its porous graphene surface, while neither a significant surface chemistry alteration nor a pore structure degradation was observed due to the Pt decoration procedure. The presence of Pt seems to slightly promote the hydrogen sorption behavior at room temperature with respect to the pure graphene, thus implying the rise of "weak" chemisorption phenomena, including a potential hydrogen "spillover" effect. The findings of this experimental study provide insights for the development of novel graphene-based nanocomposites for hydrogen storage applications at ambient conditions. (C) 2020 The Authors. Published by Elsevier Ltd.