• 文献标题:   CuO/Graphene Oxide Nanocomposite as Highly Active and Durable Catalyst for Selective Oxidation of Cyclohexane
  • 文献类型:   Article
  • 作  者:   RANA S, JONNALAGADDA SB
  • 作者关键词:   copper oxide, cyclohexane, cyclohexanone, graphene oxide, selective oxidation
  • 出版物名称:   CHEMISTRYSELECT
  • ISSN:   2365-6549
  • 通讯作者地址:   Univ KwaZulu Natal
  • 被引频次:   6
  • DOI:   10.1002/slct.201601637
  • 出版年:   2017

▎ 摘  要

Achieving breakage of C-H bond of hydrocarbons performance still remains a significant challenge in oxidation chemistry for heterogeneous catalyst. In this work, we report copper oxide-graphene oxide (CuO-GO) nanocomposites as durable and highly active and selective catalyst for oxidation of cyclohexane. Different wt% of Cu(II) loaded on RGO surface to form a nanocomposite as well as Co(II) and Ni(II) loaded GO composites were prepared by wet impregnation method. The efficacy of catalyst was tested towards selective oxidation of cyclohexane. 5wt% CuO-GO proved to be superior in terms improved selectivity towards cyclohexanone (82%) and short reaction times, plus easy recovery and reusability of the catalyst. The presence of functional groups prevent the aggregation of catalytically active CuO species during the reaction progress.