• 文献标题:   Field emission of graphene oxide decorated ZnO nanorods grown on Fe alloy substrates
  • 文献类型:   Article
  • 作  者:   DING JJ, CHEN HX, MA L, FU HW, WANG XJ
  • 作者关键词:   graphene oxide, zno nanorod, field emission, emission mechanism
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:   Xian Shiyou Univ
  • 被引频次:   6
  • DOI:   10.1016/j.jallcom.2017.09.216
  • 出版年:   2017

▎ 摘  要

Graphene oxides (GO) are decorated on the top surface of ZnO nanorods (NRs) grown on Fe alloy substrates for efficient field emission. The GO decorated ZnO NRs acting as cold electron emitters exhibit excellent field emission performance with the turn-on field E-to as low as 1.63 V/mu m and the threshold field E-thr down to 3.12 V/mu m. ZnO NRs grown on the alloy substrates have a low interfacial resistance and intend to enhance electrical conduction. A schottky contact of Fe-ZnO and matched Fermi levels of ZnO-GO interface contribute to the enhanced current emission efficiency. Besides, some nanometer-scaled sharp protrusions have been formed in the GO sheets, and GO itself owns abundant C-O-C oxygen functional groups that also help to improve the field emission current. A straight line Fowler-Nordheim plot of the field emission current from the emitter is obtained and the effective work function for the decorated GO sheets is calculated from the slope with a value below 1.5 eV. Finally, field emission mechanism of the GO decorated ZnO NRs has been proposed. This work may help the development of the practical electron sources and advanced optronic devices based on GO field emitters. (C) 2017 Elsevier B.V. All rights reserved.