• 文献标题:   A green approach for the development of functionalized graphene and cardanol-based polybenzoxazine nanocomposite
  • 文献类型:   Article
  • 作  者:   SAMBANDAM S, NALLAMUTHU P, SARASWATHI JL
  • 作者关键词:   functionalized graphene, nanocomposite, polybenzoxazine, specific capacitance
  • 出版物名称:   POLYMER COMPOSITES
  • ISSN:   0272-8397 EI 1548-0569
  • 通讯作者地址:  
  • 被引频次:   3
  • DOI:   10.1002/pc.26150 EA JUN 2021
  • 出版年:   2021

▎ 摘  要

A new facile synthesis of functionalized graphene (fg-p) reinforced bio-based polybenzoxazine nanocomposite (pbf2%-pbf10%) was developed in this work. Cardanol, formaldehyde, and furfuryl amine were used to make a bio-based benzoxazine monomer (bf). bf and benzoxazine polymer (pbf) were characterized by Fourier transform infrared (FT-IR) and nuclear magnetic resonance spectroscopies, and fg-p was characterized by FT-IR spectroscopy, X-ray diffraction, and scanning electron microscopy. The electrochemical properties of the fg-p sheets and their nanocomposites (pbf2%-pbf10%) were examined using cyclic voltammetry and electrochemical impedance spectroscopy. The results of electrochemical measurements showed that pbf4% has the largest specific capacitance of 78.2 F/g when compared to pbf (36.98 F/g), which shows that fg-p reinforced pbf nanocomposites have potential application as the high-performance capacitor electrode material.