• 文献标题:   Fabrication of Cobalt Sulfide/Graphene Sheets Nanocomposite Harvesting Improved Anode Performance for Lithium-Ion Battery
  • 文献类型:   Article
  • 作  者:   ZHU J, JIN MH, TANG S
  • 作者关键词:   cobalt sulfide, graphene sheet, nanocomposite, anode material, lithiumion battery
  • 出版物名称:   JOURNAL OF NANOSCIENCE NANOTECHNOLOGY
  • ISSN:   1533-4880 EI 1533-4899
  • 通讯作者地址:   Jiangsu Univ Sci Technol
  • 被引频次:   1
  • DOI:   10.1166/jnn.2019.16520
  • 出版年:   2019

▎ 摘  要

A cobalt sulfide (CoS)/graphene sheets (GS) nanocomposite was successfully synthesized through a simple one-pot hydrothermal route assisted by ethylenediamine. The crystalline phase, structure and morphology of this nanocomposite were systematically characterized via X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), nitrogen (N-2) absorption-desorption isotherm, Raman spectroscopy and thermogravimetric analysis (TGA). The results revealed that the CoS nanoparticles with size distribution of 30-100 nm were highly dispersed on or well anchored in the creasy GS substrate. Integrating nanosized CoS compound and GS outstanding merits, the as-obtained CoS/GS nanocomposite as an anode material for lithium-ion battery exhibited high reversible capacity, excellent long-cycle stability and remarkable high-rate capability, which were all superior to those of pristine CoS. Moreover, this nanocomposite maintained a high capacity of similar to 600 mAh . g(-1) after 200 cycles at a current density of 100 mA . g(-1). The approach presented in this work is readily applicable to nanoparticle decoration of graphene sheets and preparation of other graphene-based nanocomposites as anode materials for lithium-ion batteries.