• 文献标题:   Discrete Dynamics of Nanoparticle Channelling in Suspended Graphene
  • 文献类型:   Article
  • 作  者:   BOOTH TJ, PIZZOCCHERO F, ANDERSEN H, HANSEN TW, WAGNER JB, JINSCHEK JR, DUNINBORKOWSKI RE, HANSEN O, BOGGILD P
  • 作者关键词:   graphene, graphene membrane, silver nanopartide, catalysi, channelling
  • 出版物名称:   NANO LETTERS
  • ISSN:   1530-6984
  • 通讯作者地址:   DTU Nanotech
  • 被引频次:   43
  • DOI:   10.1021/nl200928k
  • 出版年:   2011

▎ 摘  要

We have observed a previously undescribed stepwise oxidation of mono- and few layer suspended graphene by silver nanoparticles in situ at subnanometer scale in an environmental transmission electron microscope. Over the range of 600-850 K, we observe crystallographically oriented channelling with rates in the range 0.01-1 nm/s and calculate an activation energy of 0.557 +/- 0.016 eV. We present a discrete statistical model for this process and discuss the implications for accurate nanoscale patterning of nanoscale systems.