• 文献标题:   Bifunctional Material with Organic Pollutant Removing and Antimicrobial Properties: Graphene Aerogel Decorated with Highly Dispersed Ag and CeO2 Nanoparticles
  • 文献类型:   Article
  • 作  者:   TAO XF, ZHOU YZ, XU K, WU YY, MI JL, LI Y, LIU QQ, CHENG XN, ZHAO N, SHI HF, YANG J
  • 作者关键词:   graphene aerogel, cerium dioxide ceo2, silver nanoparticles ag nps, photocatalyst, antimicrobial material
  • 出版物名称:   ACS SUSTAINABLE CHEMISTRY ENGINEERING
  • ISSN:   2168-0485
  • 通讯作者地址:   Jiangsu Univ
  • 被引频次:   2
  • DOI:   10.1021/acssuschemeng.8b04251
  • 出版年:   2018

▎ 摘  要

The graphene aerogels supporting Ag and CeO2 nanoparticles (NPs) (Ag/CeO2/GA) with bifunctional performances have been fabricated by a modified gelatinization reaction method. Through the control of GO concentration and ultrasonic-assisted prereduction process, the small NPs can be dispersed highly into the porous structure of GA. The integration of a hierarchical porous structure and a synergistic effect between CeO2 and Ag NPs grant them bifunctional properties of organic pollutant removing (100% of methylene blue and 81.8% of bisphenol A were degraded within 12 min and 4 h, respectively), and antimicrobial activity against Escherichia coli (MIC100%Ag = 7.5 ppm; MBC100%Ag = 11.3 ppm). The possible mechanism is the improved photocatalytic performance of CeO2/GA by a unique surface plasmonic effect of Ag NPs due to increasing light absorption and photoconductivity for photoexcited holes and electrons. Therefore, the holes and radicals (especially center dot OH) can be produced continuously and efficiently from Ag/CeO2/GA, which can remove organic pollution from water efficiently, while protecting the water from bacterial pollution. Moreover, a good recycling stability bifunctional material has a great promise in water purification applications. and biocompatibility suggest that such