• 文献标题:   Fe-PNP Pincer Complex Immobilized on Graphene Oxide as a Catalyst for Suzuki-Miyaura Coupling Reactions
  • 文献类型:   Article
  • 作  者:   KUMAR LM, MISHRA P, BHAT BR
  • 作者关键词:   fepnp pincer complex, heterogenous catalyst, suzukimiyaura crosscoupling
  • 出版物名称:   CATALYSIS LETTERS
  • ISSN:   1011-372X EI 1572-879X
  • 通讯作者地址:   Natl Inst Technol Karnataka
  • 被引频次:   4
  • DOI:   10.1007/s10562-019-02652-7
  • 出版年:   2019

▎ 摘  要

Fe-PNP pincer complexes are the upcoming homogenous catalyst for organic reactions to overcome the need of much expensive Pd based catalysts. However, the lack of recovery and reusability are two significant challenges for homogeneous catalysts. We report herein a Fe-PNP complex immobilized on graphene oxide as a heterogeneous catalyst for the Suzuki coupling reactions. The prepared composite showed remarkable conversion efficiency towards Suzuki coupling reaction between phenylboronic acid and aryl halides. The study also discusses the parameters that are affecting the coupling reaction. The proposed catalyst can be quickly recovered and reused without any significant reduction in performance.