• 文献标题:   Electrochemical characteristics of graphene/manganese oxide composite catalyst for Li-oxygen rechargeable batteries
  • 文献类型:   Article
  • 作  者:   KALUBARME RS, AHN CH, PARK CJ
  • 作者关键词:   lio2 battery, graphene, manganese oxide, surface area
  • 出版物名称:   SCRIPTA MATERIALIA
  • ISSN:   1359-6462
  • 通讯作者地址:   Chonnam Natl Univ
  • 被引频次:   25
  • DOI:   10.1016/j.scriptamat.2012.12.020
  • 出版年:   2013

▎ 摘  要

Graphene/MnO2 composite was obtained by hydrothermal oxidation of the Mn-precursor on a graphene surface. The composite showed a fine dispersion of MnO2 nanorods over graphene nanosheets (GNs). The addition of MnO2 to GNs accelerated the oxygen reduction in the cathodes of Li-O-2 cells and promoted Li2O2 catalysis efficiently, compared with the pristine GNs. The power densities of the composite and the pristine GNs were 13.27 and 9.72 mW cm(-2), respectively. In addition, the cell containing GNs/MnO2 electrode exhibited stable cyclic performance. (c) 2012 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.