▎ 摘　　要

The design and preparation of highly efficient and durable non-noble metal electrocatalysts for overall water splitting is pivotal for actualizing large-scale water splittingviaelectrolysis. Herein, porous Ni0.85Se nanospheres anchored on reduced graphene oxide (RGO) (Ni0.85Se/RGO) were synthesizedviaa one-step hydrothermal method. Following explorations of the hydrothermal temperature and reaction time, the optimized Ni0.85Se/RGO exhibited extraordinary oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) performance in 1.0 M KOH solution, providing an overpotential as small as 320 mV at a current density of 30 mA cm(-2)and a low Tafel slope of 91 mV dec(-1)for the OER, and an overpotential of 169 mV at a current density of 10 mA cm(-2)and a low Tafel slope of 65 mV dec(-1)for the HER. A current density of 10 mA cm(-2)at 1.64 V and high stability can be obtained upon using Ni0.85Se/RGO as both the cathode and anode for overall water splitting under alkaline conditions; this was attributed to the merits of both the porous structure of Ni0.85Se and the high conductivity of RGO. This work provides a meaningful exploration of the synthesis of 3d-transition-metal-chalcogenide- and carbon-based composite electrocatalystsviaa hydrothermal reaction for water splitting, and provides a general method.