• 文献标题:   Bimetallic Antimony-Vanadium Oxide Nanoparticles Embedded in Graphene for Stable Lithium and Sodium Storage
  • 文献类型:   Article
  • 作  者:   HAO YT, JIANG Y, ZHAO LZ, YE ZQ, WANG ZH, CHU DT, WU F, LI L, XIE M, CHEN RJ
  • 作者关键词:   graphene, sbvo4, synergistic effect, lithiumion batterie, sodiumion batterie
  • 出版物名称:   ACS APPLIED MATERIALS INTERFACES
  • ISSN:   1944-8244 EI 1944-8252
  • 通讯作者地址:  
  • 被引频次:   9
  • DOI:   10.1021/acsami.0c21676 EA APR 2021
  • 出版年:   2021

▎ 摘  要

Bimetallic oxides have received considerable attention as anodes for lithium/sodium-ion batteries (LIBs/SIBs) due to their high electrochemical activity and theoretical specific capacity. However, their cycling performance is limited by large volume variation, severe aggregation, and pulverization of bimetallic oxide nanoparticles during repeated metal ion insertion/extraction processes. Herein, bimetallic antimony-vanadium oxide nanoparticles embedded in graphene (SbVO4/G) composites are prepared by a one-step hydrothermal method. Bimetallic SbVO4 with abundant redox reaction sites can provide high specific capacity by a multi-electron reaction. A robust graphene substrate can not only alleviate volume expansion but also prevent aggregation and collapse of highly active bimetallic SbVO4. Due to the excellent synergy between the two building components, SbVO4/G hybrids exhibit excellent electrochemical activity, structural stability, and electrochemical performance. When employed as anodes for LIBs and SIBs, SbVO4/G composites display excellent cycling performance (1079.5 mAh g(-1) at 0.1 A g(-1) after 150 cycles for LIBs and 401.6 mAh g(-1) at 0.1 A g(-1) after 450 cycles for SIBs) and impressive rate capability. This work demonstrates that SbVO4/G composites are promising anodes for both LIBs and SIBs.