• 文献标题:   Noncovalently copper-porphyrin functionalized reduced graphene oxide for sensitive electrochemical detection of dopamine
  • 文献类型:   Article
  • 作  者:   HUANG DL, WANG J, YUAN HQ, GUO HS, YING X, ZHANG H, LIU HY
  • 作者关键词:   graphene, porphyrin, copper, dopamine, electrochemical sensor
  • 出版物名称:   JOURNAL OF PORPHYRINS PHTHALOCYANINES
  • ISSN:   1088-4246 EI 1099-1409
  • 通讯作者地址:   South China Univ Technol
  • 被引频次:   0
  • DOI:   10.1142/S1088424618500761
  • 出版年:   2018

▎ 摘  要

The nanocomposite of an electron-deficient flat tetrakis-(ethoxycarbonyl) porphyrin copper(II) (Cu-TECP) and reduced grapheme oxide (RGO) was prepared and used for electrochemical detection of dopamine (DA). The prepared nanocomposite was characterized by scanning electron microscopy, Raman spectroscopy, FT-IR spectroscopy, ultraviolet-visible spectroscopy and electrochemical impedance spectroscopy. Electrochemical studies of the modified glass carbon electrode (GCE) were carried out by the cyclic voltammetry and differential pulse voltammograms (DPV) methods. The RGO/Cu-TECP/GCE exhibited enhanced electrocatalytic activity towards the detection of dopamine (DA). The detection limit was 0.58 mu M, while the linear range was from 2 to 200 mM (R-2 = 0.997).