• 文献标题:   N-doped ordered mesoporous carbon/graphene composites with supercapacitor performances fabricated by evaporation induced self-assembly
  • 文献类型:   Article
  • 作  者:   SUI LN, WANG YT, JI WB, KANG HQ, DONG LF, YU LY
  • 作者关键词:   ndoped, ordered mesoporous carbon/graphene composite, high surface area, graphitization, supercapacitor performance
  • 出版物名称:   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
  • ISSN:   0360-3199 EI 1879-3487
  • 通讯作者地址:   Qingdao Univ Sci Technol
  • 被引频次:   20
  • DOI:   10.1016/j.ijhydene.2017.10.113
  • 出版年:   2017

▎ 摘  要

N-doped ordered mesoporous carbon/graphene composites with supercapacitor performance are successful synthesized by evaporation induced self-assembly (EISA). In this procedure, using phenolic resin as carbon source, triblock copolymer (F127) as template, hydrochloric acid as catalyst, tetraethylorthosilicate (TEOS) as structure enhancer agent and urea as additive for improving graphitization and surface wettability, ordered mesoporous carbon is formed by EISA and low temperature carbonization. At the same time, graphene is added into the mixed solution with the carbon source. Transmission electron microscopy (TEM), small-angle X-ray diffraction (XRD) and N-2 sorption analysis results illustrate that the samples display two-dimensional ordered mesoporous structure with uniform pore diameter (similar to 4 nm). The highest surface area could reach to 1801 m(2)/g and the biggest pore volume can be up to 1.55 cm(3)/g. The reinforcement of graphitization is implied by the Raman spectroscopy and wide-angle XRD results. The capacitor performance test shows a capacitance of 246 F/g at 1 A/g with excellent stability. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.