• 文献标题:   Visualization of graphene grain boundaries through oxygen intercalation
  • 文献类型:   Article
  • 作  者:   BOKAI KA, SHEVELEV VO, MARCHENKO D, MAKAROVA AA, MIKHAILOVSKII VY, ZAKHAROV AA, VILKOV OY, KRIVENKOV M, VYALIKH DV, USACHOV DY
  • 作者关键词:   graphene, oxygen, grain boundarie, xray photoemission spectroscopy, photoemission electron microscopy, scanning electron microscopy
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:  
  • 被引频次:   3
  • DOI:   10.1016/j.apsusc.2021.150476 EA JUL 2021
  • 出版年:   2021

▎ 摘  要

Efficient control over the grain boundaries (GBs) is a vital aspect in optimizing the graphene growth conditions. A number of methods for visualization of GBs were developed for graphene grown on weakly interacting surfaces. Here, we utilize oxygen intercalation to reveal GBs and study their morphology for graphene strongly bound to the cobalt surface. We demonstrate that upon the intercalation of oxygen, GBs in polycrystalline graphene become easily detectable due to graphene cracking and selective oxidation of the substrate, thus giving a direct insight into the graphene micro-and nanostructure by means of different electron microscopy methods, including scanning electron microscopy, photoemission microscopy and low-energy electron microscopy.