• 文献标题:   High reversible capacity of SnO2/graphene nanocomposite as an anode material for lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   LIAN PC, ZHU XF, LIANG SZ, LI Z, YANG WS, WANG HH
  • 作者关键词:   graphene sheet, sno2 nanoparticle, nanocomposite, anode material, lithiumion batterie
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   S China Univ Technol
  • 被引频次:   300
  • DOI:   10.1016/j.electacta.2011.01.126
  • 出版年:   2011

▎ 摘  要

A gas-liquid interfacial synthesis approach has been developed to prepare SnO2/graphene nanocomposite. The as-prepared nanocomposite was characterized by X-ray diffraction, field emission scanning electron microscopy, transmission electron microscopy, and Brunauer-Emmett-Teller measurements. Field emission scanning electron microscopy and transmission electron microscopy observation revealed the homogeneous distribution of SnO2 nanoparticles (2-6 nm in size) on graphene matrix. The electrochemical performances were evaluated by using coin-type cells versus metallic lithium. The SnO2/graphene nanocomposite prepared by the gas-liquid interface reaction exhibits a high reversible specific capacity of 1304 mAh g(-1) at a current density of 100 mA g(-1) and excellent rate capability, even at a high current density of 1000 mA g(-1), the reversible capacity was still as high as 748 mAh g(-1). The electrochemical test results show that the SnO2/graphene nanocomposite prepared by the gas-liquid interfacial synthesis approach is a promising anode material for lithium-ion batteries. (c) 2011 Elsevier Ltd. All rights reserved.