• 文献标题:   Investigation on graphene and Pt co-modified CdS nanowires with enhanced photocatalytic hydrogen evolution activity under visible light irradiation
  • 文献类型:   Article
  • 作  者:   CAO MH, WANG PF, AO YH, WANG C, HOU J, QIAN J
  • 作者关键词:  
  • 出版物名称:   DALTON TRANSACTIONS
  • ISSN:   1477-9226 EI 1477-9234
  • 通讯作者地址:   Hohai Univ
  • 被引频次:   23
  • DOI:   10.1039/c5dt02266e
  • 出版年:   2015

▎ 摘  要

Hydrogen evolution by photocatalytic water splitting has attracted extensive attention in recent years. Here we report a composite photocatalyst, in which graphene and Pt particles act as cocatalysts to modify CdS nanowires. This composite photocatalyst was prepared by a solvothermal method followed by a photoreduction process. The obtained samples were characterized by X-ray powder diffraction, UV-vis diffuse reflectance spectroscopy, scanning and transmission electron microscopy, X-ray photoelectron spectroscopy, photoluminescence and Brunauer-Emmett-Teller specific surface area analysis. The graphene and Pt comodified CdS nanowires gain a high hydrogen evolution rate of 3984 mu mol h(-1) g(-1), which is almost 4 times higher than that of bare CdS nanowires and also higher than the sum of graphene-CdS and Pt-CdS nanowires. The obtained sample also exhibits a good stability. The encouraging results presented here can be attributed to the incorporation of graphene and Pt which show a synergetic effect for hydrogen evolution. This work paves a way to the potential application of CdS nanowires in energy conversion.