• 文献标题:   Enhanced electrochemical detection of iodide at a reduced graphene oxide-modified carbon electrode in iodized salts
  • 文献类型:   Article
  • 作  者:   JAMILAN MA, ABDULLAH J, AHMAD SAA, NOH MFM
  • 作者关键词:   electrochemical, reduced graphene oxide, iodide, salt sample, ionpairing
  • 出版物名称:   FOOD CHEMISTRY
  • ISSN:   0308-8146 EI 1873-7072
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1016/j.foodchem.2022.133382 EA JUN 2022
  • 出版年:   2022

▎ 摘  要

In this study, enhancement of electrochemical performance of electrochemically reduced graphene oxide (ERGO) on a screen-printed carbon electrode (SPCE) (ERGO/SPCE) coupled with ion-pairing (cetyltrimethylammonium bromide, CTAB) for the determination of iodide in table salt has been described. The electrode modification of ERGO/SPCE was conducted using cyclic voltammetric (CV) scanning in the potential range of 1.3-0.4 V for 50 cycles after the drop-casting of graphene oxide (GO) suspension on the SPCE. It was found that the electro-active surface area of ERGO/SPCE was increased by 1.5-fold compared to the bare SPCE. ERGO/SPCE sensor displays linearity towards iodide in the concentration range from 0.020 to 1.0 mg/L (sensitivity = 5.40 mu A(mg/L)(-1), R-2 = 0.9906) with the limit of detection (LOD) and limit of quantitation (LOQ) of 0.070 mg/L and 0.21 mg/L, respectively. The comparison between polarography and ERGO/SPCE sensor was in good agreement.