• 文献标题:   Enhanced Cycling Performance for Lithium-Sulfur Batteries by a Laminated 2D g-C3N4/Graphene Cathode Interlayer
  • 文献类型:   Article
  • 作  者:   QU L, LIU P, YI YK, WANG T, YANG P, TIAN XL, LI MT, YANG BL, DAI S
  • 作者关键词:   batterie, carbon nitride, graphene, lithium, sulfide
  • 出版物名称:   CHEMSUSCHEM
  • ISSN:   1864-5631 EI 1864-564X
  • 通讯作者地址:   Xi An Jiao Tong Univ
  • 被引频次:   21
  • DOI:   10.1002/cssc.201802449
  • 出版年:   2019

▎ 摘  要

Decay in electrochemical performance resulting from the "shuttle effect" of dissolved lithium polysulfides is one of the biggest obstacles for the realization of practical applications of lithium-sulfur (Li-S) batteries. To meet this challenge, a 2D g-C3N4/graphene sheet composite (g-C3N4/GS) was fabricated as an interlayer for a sulfur/carbon (S/KB) cathode. It forms a laminated structure of channels to trap polysulfides by physical and chemical interactions. The thin g-C3N4/GS interlayer significantly suppresses diffusion of the dissolved polysulfide species (Li2Sx; 2