• 文献标题:   A simple method of preparing graphene-coated Li[Li0.2Mn0.13Co0.13]O-2 for lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   HE ZJ, WANG ZX, GUO HJ, LI XH, WU XW, YUE P, WANG JX
  • 作者关键词:   lithiumion batterie, surface, graphene coating, microstructure
  • 出版物名称:   MATERIALS LETTERS
  • ISSN:   0167-577X
  • 通讯作者地址:   Cent S Univ
  • 被引频次:   28
  • DOI:   10.1016/j.matlet.2012.09.115
  • 出版年:   2013

▎ 摘  要

Graphene-coated Li[Li0.2Mn0.13Co0.13]O-2 is synthesized by the spray drying method. The morphology and electrochemical performances of the pristine and graphene-coated cathodes have been investigated by scanning electron microscopy (SEM), transmission electron microscopy (TEM), charge-discharge measurements, as well as Ac impedance spectroscopy. At 250 mA g(-1), the pristine and graphene-coated samples deliver capacities of similar to 141 and 153 mAh g(-1) with capacity retention of 80 and 97% in 50 cycles, respectively. An analysis of the charge-discharge capacity values and electrochemical impedance spectroscopy (EIS) measurements reveal that the improved electrochemical performances of the graphene-coated sample are due to the suppression of the solid-electrolyte interfacial (SEI) layer and the enhancement of surface electronic conductivity. (C) 2012 Elsevier B.V. All rights reserved.