• 文献标题:   Synthesis of engineered graphene nanocomposites coated with NiCo metal-organic frameworks as electrodes for high-quality supercapacitor
  • 文献类型:   Article
  • 作  者:   ANDIKAEY Z, ENSAFI AA, REZAEI B
  • 作者关键词:   graphene, glucose, nicomof, surface engineering, supercapacitor
  • 出版物名称:   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
  • ISSN:   0360-3199 EI 1879-3487
  • 通讯作者地址:   Isfahan Univ Technol
  • 被引频次:   0
  • DOI:   10.1016/j.ijhydene.2020.08.004
  • 出版年:   2020

▎ 摘  要

Metal-organic frameworks (MOF) are a novel generation of promising electrodes for supercapacitors. The synthesis of glucose modified, high-quality graphene (HQG) as a platform for the nucleation and growth of bimetallic MOF nanosheets (NiCo-MOF) is reported. The -COOH and -OH groups formed on the surface, thus enhance the interaction between the HQG and NiCo-MOF. This heterostructure is used as an electrode in the preparation of asymmetric supercapacitors with a capacity of 244 F/g and an energy density of 76.3 W h/g. The nanocomposite also exhibits a high specific capacitance of 4077.3 F/g at a current density of 2.5 A/g. Therefore, new approaches have been introduced for the fabrication of efficient supercapacitors, and a step forward has been taken for the development of other electrical applications, including batteries, fuel cells, catalysts, and types of sensors. (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.