• 文献标题:   Effects of underlayer on the reduction of graphene oxide through atomic hydrogen annealing and soft X-ray irradiation
  • 文献类型:   Article
  • 作  者:   HEYA A, FUJIBUCHI A, HIRATA M, KANDA K, MATSUO Y, INAMOTO J, SUMITOMO K
  • 作者关键词:   graphene oxide, reduction, atomic hydrogen, soft xray, reduced graphene oxide
  • 出版物名称:   JAPANESE JOURNAL OF APPLIED PHYSICS
  • ISSN:   0021-4922 EI 1347-4065
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.35848/1347-4065/acac37
  • 出版年:   2023

▎ 摘  要

The reduction of graphene oxide (GO) through atomic hydrogen annealing (AHA) and soft X-ray irradiation is investigated using microwell substrates with mu m-sized holes with and without Ni underlayers. The GO film is reduced through AHA at 170 degrees C and soft X-ray irradiation at 150 degrees C. In contrast, some GO films are not only reduced but also amorphized through soft X-ray irradiation. The effect of the Ni underlayer on GO reduction differs between AHA and soft X-ray irradiation. In AHA, the difference in GO reduction between SiO2 and Ni underlayer originates from the atomic hydrogen density on the sample surface. On the other hand, in soft X-ray irradiation, the difference in GO reduction between SiO2 and the Ni underlayer originates from the excited electrons generated by soft X-ray irradiation. Reduction without damage is more likely to occur in the suspended GO than in the supported GO.