• 文献标题:   Thermal Oxidation and Unwrinkling of Chemical Vapor Deposition-Grown Graphene
  • 文献类型:   Article
  • 作  者:   SURWADE SP, LI ZT, LIU HT
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF PHYSICAL CHEMISTRY C
  • ISSN:   1932-7447
  • 通讯作者地址:   Univ Pittsburgh
  • 被引频次:   46
  • DOI:   10.1021/jp306537y
  • 出版年:   2012

▎ 摘  要

We report the atmospheric thermal oxidation of chemical vapor deposition (CVD)-grown graphene and its effect on the wrinkles in graphene. Heating CVD-grown single-layer graphene in air at 550 degrees C leads to the disappearance of the wrinkles and the formation of nanoscale cracks and pits in the basal plane. Under this reaction condition, the wrinkles were not preferentially attacked by O-2, which we attribute to the relaxation of wrinkles as well as the presence of more reactive point defects and grain boundaries in the basal plane. Randomly stacked two-layer graphene was found to be more stable toward oxidation than was single-layer graphene.