▎ 摘　　要

Graphene quantum dots (GQDs) have shown great potential to simultaneously improve the stability and efficiency of perovskite solar cells (PSCs). However, their preparation is either extremely harsh or inefficient, which severely hampers the extensive research and application. Herein, a novel solid-liquid interfacial exfoliation technique is established to fabricate high-quality GQDs from carbon fiber, in which the throughput of GQDs is up to 20 g in one pot with yield over 90%. To explore their role in PSC, nitrogen and sulfur functionalized GQDs have been further synthesized via a hydrothermal method, and used to regulate the interfacial properties of all-inorganic CsPbIBr2 PSC. Arising from the interaction based on Lewis acidbase chemistry between GQDs and the under-coordinated Pb2+, the detrimental non-radiative recombination is significantly reduced, especially for the functionalized GQDs tailored PSC, leading to the champion efficiency of 9.80% for carbon-electrode based CsPbIBr2 PSCs with excellent long-term stability. (c) 2021 Elsevier B.V. All rights reserved.