• 文献标题:   Assembly and superior performance of palladium nano-catalysts anchored to a magnetic konjac glucomannan-graphene oxide hybrid for H-2 generation from ammonia borane
  • 文献类型:   Article
  • 作  者:   JIA H, SONG XR, LIU S, XU X, ZHENG XC, PENG ZK, LIU P
  • 作者关键词:   konjac glucomannan, graphene oxide, palladium nanoparticle, magnetic catalyst, hydrolytic dehydrogenation, ammonia borane
  • 出版物名称:   JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS
  • ISSN:   1876-1070 EI 1876-1089
  • 通讯作者地址:   Zhengzhou Univ
  • 被引频次:   7
  • DOI:   10.1016/j.jtice.2019.04.013
  • 出版年:   2019

▎ 摘  要

As important multifunctional materials, the organic-inorganic hybrids are expected to be widely used in many fields, such as biosensor, solar cell and heterogeneous catalysis. In this article, we assemble a magnetic hybrid consisting of konjac glucomannan (KGM), graphene oxide (GO) and ferroferric oxide (Fe3O4) via a co-precipitation method to anchor palladium nanoparticles. The resultant Pd/KGM-GO-Fe3O4 catalysts exhibit superior catalytic performance for the hydrolysis of ammonia borane. The corresponding turnover frequency (TOF) is as high as 40.1 mol(H2) mol(pd)(-1) min(-1) in addition to a low activation energy (E-a = 26.1 kJ mol(-1)). The high catalytic activity is still maintained in the 10th recycle run, demonstrating their outstanding reusability. In addition, the magnetism of Fe3O4 and the unique structure of the resultant catalysts achieve effective momentum transfer in an external magnetic field, endowing the easy separation of the catalysts from the reaction system with an external magnet. The results will facilitate the development of both H-2 generation and organic-inorganic hybrid-based materials. (C) 2019 Taiwan Institute of Chemical Engineers. Published by Elsevier B.V. All rights reserved.