• 文献标题:   Synthesis and performance of a graphene decorated NaTi2(PO4)(3)/C anode for aqueous lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   JIANG Z, LI YH, ZHU J, LI B, LI CC, WANG L, MENG W, HE ZX, DAI L
  • 作者关键词:   aqueous lithiumion batterie, anode, nati2 po4 3, graphene, electrochemical performance
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:   North China Univ Sci Technol
  • 被引频次:   41
  • DOI:   10.1016/j.jallcom.2019.03.289
  • 出版年:   2019

▎ 摘  要

Aqueous lithium-ion batteries (ALIBs) possess significant potential in applications as large-scale energy storage systems and portable power sources. Nevertheless, the inferior performance of the anodes significantly restricts the extensive applications of ALIBs. Herein, a graphene decorated NaTi2(PO4)(3)/C (NTP/C-G) composite was synthesized by sol-gel technology and applied as a high-performance anode for ALIBs. There was no significant impact on the crystal lattice frame of NaTi2(PO4)(3) with the graphene modification. Graphene possessing a large surface area and good conductivity improved the electrochemical performance of the as-prepared NaTi2(PO4)(3)/C (NTP/C) composite. The discharge capacity of the NTP/C-G parallel to LiMn2O4 cell reached 107.8, 86.2, and 76.9 mAh g(-1) at 0.5,10, and 15C, respectively, which was 12, 18.8, and 19.3 mAh g(-1) higher than those for the original NTP/C parallel to LiMn2O4 cell. Moreover, the capacity retention of the NTP/C-G parallel to LiMn2O4 cell at 6C retained 92.1% after 1,000 cycles, which was much higher than that for the original NTP/C parallel to LiMn2O4 cell (69.1%). The excellent performance of the graphene decorated composite was mainly attributed to the formation of conductive networks. Our data showed that graphene decorated NaTi2(PO4)(3)/C was a prospective anode for ALIBs. (C) 2019 Elsevier B.V. All rights reserved.