• 文献标题:   Quasi in-situ observation of the elastic properties changes of the graphene-low-density polyethylene composites
  • 文献类型:   Article
  • 作  者:   GAJEWSKI K, SZYMANSKI W, KACZOROWSKI W, NIEDZIELSKI P, GOTSZALK T
  • 作者关键词:   graphene, hsmg, elastic propertie, kpfm, raman spectroscopy
  • 出版物名称:   DIAMOND RELATED MATERIALS
  • ISSN:   0925-9635 EI 1879-0062
  • 通讯作者地址:   Wroclaw Univ Sci Technol
  • 被引频次:   0
  • DOI:   10.1016/j.diamond.2018.01.014
  • 出版年:   2018

▎ 摘  要

In this paper we present the results of electromechanical studies of graphene low-density polyethylene (LDPE) composites. Two types of graphene were transferred onto LDPE using PMMA support: graphene grown by physical vapor deposition on liquid metallic matrix (so called high strength metallurgical graphene, HSMG) and commercial chemical vapor deposited (CVD) graphene. Raman spectroscopy was used for preliminary characterization of graphene, whereas Kelvin probe force microscopy (KPFM) combined with electrical measurement setup and symmetrical stretching stage was used for observations of the electrical properties changes of elongated graphene. Maximum elongation of graphene LDPE composites were 10%. Resistance of the HSMG graphene was changing from 130 k Omega up to 900 k Omega for HSMG graphene and from 100 k Omega up to 300 k Omega for CVD graphene. Observed resistance changes were compared with contact potential difference recorded by KPFM. KPFM showed that resistance changes can be attributed rather to the structural discontinuities for the CVD graphene sample. In case of the HSMG graphene sample such behavior was not observed.