• 文献标题:   A facile method for preparing nitrogen-doped graphene and its application in supercapacitors
  • 文献类型:   Article
  • 作  者:   JIN H, WANG XM, GU ZR, FAN QH, LUO B
  • 作者关键词:   ndoped graphene, surface area, pore structure, supercapacitor, biochar
  • 出版物名称:   JOURNAL OF POWER SOURCES
  • ISSN:   0378-7753 EI 1873-2755
  • 通讯作者地址:   S Dakota State Univ
  • 被引频次:   40
  • DOI:   10.1016/j.jpowsour.2014.10.010
  • 出版年:   2015

▎ 摘  要

Nitrogen-doped graphene (N-doped graphene) produced from dried distillers grains with solubles (DDGS) is an extremely attractive material for energy storage due to the high specific capacitance and low cost. The as-prepared samples are derived from DDGS, an inexpensive byproduct from fermentation processed optimized for first generation bio-fuel production. The scanning electron microscopy, transmission electron microscopy results demonstrate the 700 degrees C treated sample (N-700) displays crumpled nanosheets and few-layer graphene nanostructure. XRD and Raman spectroscopy indicate N-700 presents the distinctive graphene diffraction peaks. The XPS of N-700 shows the N 1s can be split into pyrrolic-N and pyridinic-N. The cyclic voltammetry, galvanostatic charge/discharge and electrochemical impedance spectroscopy were measured based on N-700. A high specific capacitance of 324 F g(-1), and a relatively low inner resistance of 0.1 Omega were obtained. (C) 2014 Elsevier B.V. All rights reserved.