• 文献标题:   Nitrogen-doped mesoporous reduced graphene oxide for high-performance supercapacitors
  • 文献类型:   Article
  • 作  者:   PHAM VH, NGUYENPHAN TD, JANG J, VU TDT, LEE YJ, SONG IK, SHIN EW, CHUNG JS
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:   2046-2069
  • 通讯作者地址:   Univ Ulsan
  • 被引频次:   17
  • DOI:   10.1039/c4ra03049d
  • 出版年:   2014

▎ 摘  要

We report a simple method to prepare N-doped mesoporous reduced graphene oxide (RGO) via the pyrolysis of poly (methyl methacrylate)-graphene oxide (PMMA-GO) and PMMA-RGO composites in a mixed nitrogen and ammoniac atmosphere. The pyrolysis of the PMMA-GO resulted in a heavily nitrogen-doped RGO aerogel with a nitrogen content of more than 5.0 at%, whereas crumpled RGO with a surface area of up to 766 m(2) g(-1) was obtained by the pyrolysis of PMMA-RGO. A supercapacitor based on the N-doped mesoporous RGOs exhibited an excellent specific capacitance of up to 290 F g(-1) at a current density of 1 A g(-1) and good electrochemical stability with a capacitance retention of about 85% after 1000 cycles. Moreover, by using an ionic liquid as an electrolyte within a potential range of 0-4 V, a remarkable energy density of up to 149 W h kg(-1) was achieved.