• 文献标题:   Identifying the Orientation of Edge of Graphene Using G Band Raman Spectra
  • 文献类型:   Article
  • 作  者:   SASAKI K, SAITO R, WAKABAYASHI K, ENOKI T
  • 作者关键词:   graphene, edge orientation, raman spectroscopy, electronphonon interaction, electronlight interaction, pseudospin, gauge field
  • 出版物名称:   JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN
  • ISSN:   0031-9015
  • 通讯作者地址:   Natl Inst Mat Sci
  • 被引频次:   36
  • DOI:   10.1143/JPSJ.79.044603
  • 出版年:   2010

▎ 摘  要

The electron-phonon matrix elements relevant to the Raman intensity and Kohn anomaly of the G band are calculated by taking into account the effect of the edge of graphene. The analysis of the pseudospin reveals that the longitudinal optical phonon mode undergoes a strong Kohn anomaly for both the armchair and zigzag edges, and that only the longitudinal (transverse) optical phonon mode is a Raman active mode near the armchair (zigzag) edge. The Raman intensity is enhanced when the polarization of the incident laser light is parallel (perpendicular) to the armchair (zigzag) edge. This asymmetry between the armchair and zigzag edges is useful in identifying the orientation of the edge of graphene.