• 文献标题:   Oxidation of styrene using TiO2-graphene oxide composite as solid heterogeneous catalyst with hydroperoxide as oxidant
  • 文献类型:   Article
  • 作  者:   SAKTHIVEL B, JOSEPHINE DSR, SETHURAMAN K, DHAKSHINAMOORTHY A
  • 作者关键词:   graphene oxide, tio2, styrene, oxidation, tbutylhydroperoxide
  • 出版物名称:   CATALYSIS COMMUNICATIONS
  • ISSN:   1566-7367 EI 1873-3905
  • 通讯作者地址:   Madurai Kamaraj Univ
  • 被引频次:   8
  • DOI:   10.1016/j.catcom.2018.01.029
  • 出版年:   2018

▎ 摘  要

The catalytic activity of TiO2 nanoparticles supported on graphene oxide (GO) namely TiO2/GO is reported in the oxidation of styrene (1) using t-butylhydroperoxide (TBHP) as an oxidant in acetonitrile at 70 degrees C. The oxidation of 1 results mainly in benzaldehyde (2) and styrene oxide (3) using TiO2/GO as catalyst using TBHP as an oxidant. Furthermore, the product selectivity of 3 increases with increasing the wt% of TiO2 on GO under the present reaction conditions. Also, the 5%TiO2/GO catalyst was recycled for four cycles without any drop in conversion of 1 under the present experimental conditions.