• 文献标题:   Platinum nanoparticles supported on reduced graphene oxide prepared in situ by a continuous one-step laser process
  • 文献类型:   Article, Proceedings Paper
  • 作  者:   HAXHIAJ I, TIGGES S, FIRLA D, ZHANG XR, HAGEMANN U, KONDO T, NAKAMURA J, MARZUN G, BARCIKOWSKI S
  • 作者关键词:   ligandfree pt np, graphene, in situ plal, nanosized material generation, particle adsorption, heterogeneous catalyst
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:   Univ Duisburg Essen
  • 被引频次:   10
  • DOI:   10.1016/j.apsusc.2018.10.257
  • 出版年:   2019

▎ 摘  要

A large research emphasis is still placed on improvement of production routes of nanosized materials with enhanced catalytic properties. Here we developed a continuous process for generation of platinum (Pt) nanoparticles supported on reduced graphene oxide (rGO) in situ via pulsed laser ablation in liquid (PLAL) dispersion of rGO. This in situ PLAL technique is a single step procedure that allows the synthesis of heterogeneous catalysts with a simultaneous control of particle size and mass loading. By this method, Pt particles with mean particle diameters around 2.5 nm and in a regime of 3-4 nm have been produced in ethanol and saline water, respectively, and adsorbed on rGO with up to 50 wt%. Both inorganic and organic solvents used during in situ synthesis lead to production of CO tolerant Pt/rGO catalysts, which are relevant for fuel cell applications due to the remarkably low CO desorption temperatures around 65-80 degrees C.