• 文献标题:   Palladium-Containing Graphene-Like Material: Synthesis and Catalytic Activity
  • 文献类型:   Article
  • 作  者:   KLYUEV MV, ARBUZOV AA, MAGDALINOVA NA, KALMYKOV PA, TARASOV BP
  • 作者关键词:   graphite oxide, graphenelike material, palladiumcontaining catalyst, liquidphase hydrogenation, nitrobenzene, cyclohexene
  • 出版物名称:   RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A
  • ISSN:   0036-0244 EI 1531-863X
  • 通讯作者地址:   Russian Acad Sci
  • 被引频次:   1
  • DOI:   10.1134/S0036024416090144
  • 出版年:   2016

▎ 摘  要

A graphene-like material with surface amine groups is obtained by graphite oxide reduction with ethylenediamine. A catalyst for the hydrogenation of nitrocompounds and unsaturated hydrocarbons is created by depositing Pd nanoparticles on the graphene material. The aliphatic chain is found to prevent agglomeration of the graphene sheets, while the amine groups form the growth centers of palladium nanoparticles, allowing their uniform distribution and small size.