• 文献标题:   High-Performance Supercapacitors Based on Poly(ionic liquid)-Modified Graphene Electrodes
  • 文献类型:   Article
  • 作  者:   KIM TY, LEE HW, STOLLER M, DREYER DR, BIELAWSKI CW, RUOFF RS, SUH KS
  • 作者关键词:   supercapacitor, electrical double layer, graphene, ionic liquid, thermal reduction, ultracapacitor
  • 出版物名称:   ACS NANO
  • ISSN:   1936-0851
  • 通讯作者地址:   Univ Texas Austin
  • 被引频次:   456
  • DOI:   10.1021/nn101968p
  • 出版年:   2011

▎ 摘  要

We report a high-performance supercapacitor incorporating a poly(ionic liquid) modified reduced; graphene oxide (PIL:RG-0) electrode and an ionic liquid (IL) electrolyte (specifically, 1-ethyl-3-methylimidazolium bis(trifluoromethylsuffonyl)amide or EMIM-NTf(2)). PIL:RG-0 provides enhanced compatibility with the IL thereby increasing the effective electrode surface area accessible to electrolyte ions. The supercapacitor assembled. with PIL:RG-0 electrode and EMIM-NTf(2) electrolyte showed a stable electrochemical response up to 35 V operating voltage and was capable of yielding a maximum energy density of 65 W . h/kg with a power density of 24 kW/kg. These results demonstrate the potential of the PIL:RG-0 material as an electrode In high-performance supercapacitors.