• 文献标题:   Fabrication of hydrogel of hydroxypropyl cellulose (HPC) composited with graphene oxide and its application for methylene blue removal
  • 文献类型:   Article
  • 作  者:   LIU XY, ZHOU YF, NIE WY, SONG LY, CHEN PP
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS SCIENCE
  • ISSN:   0022-2461 EI 1573-4803
  • 通讯作者地址:   Anhui Univ
  • 被引频次:   41
  • DOI:   10.1007/s10853-015-9166-y
  • 出版年:   2015

▎ 摘  要

Novel environmental friendly hydroxypropyl cellulose (HPC) hydrogels were fabricated upon compositing with graphene oxide (GO) in this work. In order to promote a more homogeneous dispersion of GO sheets in HPC, GO was firstly modified with HPC chains through esterification. The morphology and chemical structure of the functionalized HPC-GO were characterized by transmission electron microscopy, X-ray photoelectron spectroscopy, Fourier transform infrared spectrometer, X-ray diffraction, and thermo-gravimetric analysis. Then scanning electronic microscope was employed to compare the morphologies of the HPC and HPC-GO/HPC hydrogels. The obtained HPC-GO/HPC hydrogels exhibited excellent adsorption performance toward methylene blue. Simulation of the practical use by preparing simple adsorption columns made from in situ formation of HPC-based hydrogels had given a visible observation of the significant adsorption effect brought by the incorporation of HPC-GO sheets. Adsorption kinetics were then imitated by Lagergren pseudo-first-order and pseudo-second-order models. Adsorption isotherms were imitated by Langmuir isotherm and Freundlich isotherm.