• 文献标题:   One-step electrodeposition of reduced graphene oxide on three-dimensional porous nano nickel-copper foam electrode and its use in supercapacitor
  • 文献类型:   Article
  • 作  者:   MIRZAEE M, DEHGHANIAN C, BOKATI KS
  • 作者关键词:   electrochemically reduced graphene oxide, nicu foam, supercapacitor, porous film, electrochemical reduction
  • 出版物名称:   JOURNAL OF ELECTROANALYTICAL CHEMISTRY
  • ISSN:   1572-6657 EI 1873-2569
  • 通讯作者地址:   Univ Tehran
  • 被引频次:   6
  • DOI:   10.1016/j.jelechem.2018.02.032
  • 出版年:   2018

▎ 摘  要

A new three-dimensional (3D) porous nano-Ni-Cu foam/electrochemically reduced Graphene Oxide (ERGO) electrode for high performance supercapacitors is represented. In this study, Graphene Oxide (GO) in the form of nanosheets was deposited (0 V to -1.5 V vs. Saturated Calomel Electrode (SCE)) and reduced by cyclic voltammetry method under different scan rates in the range of 10-100 mV/s on Ni-Cu foam. Raman spectroscopy and X-ray photoelectron spectroscopy (XPS) indicated that the graphene structure was considerably restored in ERGO. ERGO deposited at the electrochemical scan rate of 50 mV/s presented the best capacitance performance. Notably, a high specific capacitance of the 1380.2 F/g at a discharge rate of 2 A/g and also an energy density of 30.01 W h kg(-1) at a power density of 10.2 kW/kg was achieved for fabricated nano-Ni-Cu foam/ERGO composite film. Moreover, the designed composite provided an excellent cycling stability, which is a very important requirement for being used as electrodes for high-performance supercapacitors. This work introduces the 3D porous nano-Ni-Cu foam/ERGO procedure an impressive approach in the direction of supercapacitors with high energy and power densities.