• 文献标题:   CeO2 Supported on Reduced Graphene Oxide as Li-O-2 Battery Cathode
  • 文献类型:   Article, Early Access
  • 作  者:   FU ZR, WANG S, YU HH, NIE ML, FENG XL, ZUO XT, FU LC, LIU DP, ZHANG Y
  • 作者关键词:   lio2 battery, cathode, ceo2 nanoparticle, reduced graphene oxide
  • 出版物名称:   CHEMICAL RESEARCH IN CHINESE UNIVERSITIES
  • ISSN:   1005-9040 EI 2210-3171
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1007/s40242-023-3107-0 EA JUN 2023
  • 出版年:   2023

▎ 摘  要

Li-O-2 battery(LOB) has an ultrahigh specific capacity(3500 W.h/kg), however, its slow kinetics of oxygen reduction reaction(ORR) and oxygen evolution reaction(OER) at cathode often leads to a high overpotential, a limited discharge capacity, and a poor cycling performance. Therefore, it is important to design and prepare cathode materials with a excellent catalytic activity. In this study, CeO2 nanoparticles(NPs) supported on reduced graphene oxide(rGO) have been prepared and employed as cathode. Compared with either CeO2 NPs or rGO, CeO2/rGO cathode greatly improves the discharge capacity(10644 mA.h/g at a current density of 100 mA/g) and the cycling performance(95 cycles at 200 mA/g with a limited capacity of 500 mA center dot h/g) by virtue of the good conductivity of rGO and the oxygen storage/release capability of CeO2.