• 文献标题:   Rapid room-temperature synthesis of Pd nanodendrites on reduced graphene oxide for catalytic oxidation of ethylene glycol and glycerol
  • 文献类型:   Article
  • 作  者:   LI SS, HU YY, FENG JJ, LV ZY, CHEN JR, WANG AJ
  • 作者关键词:   reduced graphene oxide, octylphenoxypolye thoxyethanol, nanodendrite, ethylene glycol, glycerol
  • 出版物名称:   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
  • ISSN:   0360-3199 EI 1879-3487
  • 通讯作者地址:   Zhejiang Normal Univ
  • 被引频次:   64
  • DOI:   10.1016/j.ijhydene.2013.12.159
  • 出版年:   2014

▎ 摘  要

In this paper, a simple, fast, and green method is developed for preparation of uniform Pd nanodendrites anchored on reduced graphene oxide (Pd/RGO) at room temperature, with the assistance of octylphenoxypolye thoxyethanol (NP-40) as a soft template, while no seed, organic solvent, or special apparatus involved. The as-prepared nanocomposites show the improved CO tolerance, enhanced catalytic activity, and better stability for ethylene glycol (EG) and glycerol (Gly) electrooxidation in alkaline media, compared with commercial Pd black and Pd/C catalysts. The synthetic strategy can be extended to fabricate other electrocatalysts in direct alcohol fuel cells. Copyright (C) 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.