• 文献标题:   C-C Bonding of Graphene Oxide on 4-Aminophenyl Modified Gold Electrodes towards Simultaneous Detection of Heavy Metal Ions
  • 文献类型:   Article
  • 作  者:   ZHANG Y, QI M, LIU GZ
  • 作者关键词:   aryldiazonium salt, graphene oxide, electrochemical sensor, heavy metal ion
  • 出版物名称:   ELECTROANALYSIS
  • ISSN:   1040-0397 EI 1521-4109
  • 通讯作者地址:   Cent China Normal Univ
  • 被引频次:   18
  • DOI:   10.1002/elan.201400591
  • 出版年:   2015

▎ 摘  要

This paper studied the electrochemical sensors based on C-C bonding of graphene oxide (GO) pi-conjugated aromatic group modified gold electrodes for simultaneous detection of heavy metal ions. For comparison, another sensing interface Au-Ph-NH-CO-GO, in which GO was modified to Au-Ph-NH2 interfaces by amide bonding. On the basis of the principle of heavy metal ions complexation with oxygenated species on GO, the fabricated sensing interfaces were used for the simultaneous determination of Pb2+, Cu2+ and Hg2+. The performance of two sensing interfaces for simultaneous detection of three metal ions was compared. Au-Ph-GO sensing interface demonstrated higher sensitivity and better repeatability than Au-Ph-NH-CO-GO sensing interface.