▎ 摘　　要

Interconnected mesoporous sheet-like ZnCo2O4 nanomaterials directly grown on a three-dimensional (3D) graphene film (GF) coated on Ni foam (NF) have been successfully synthesized via an effective chemical vapor deposition (CVD) method combined with a subsequent hydrothermal route. When the ZnCo2O4@(3)DGF@NF composite material with a high surface area of 46.06 m(2) g(-1) is evaluated as a binder-free anode material for lithium ion batteries, it exhibits a superior electrochemical performance with a high discharge capacity (1223 mA h g(-1) at a current density of 500 mA g(-1) after 240 cycles), and an excellent reversibility (coulombic efficiency of 97-99%). Such an outstanding electrochemical performance may be attributed to its unique mesoporous sheet-like nanostructure with a 3DGF supporting, which can facilitate the electrolyte penetration and accelerate the ion/electron transport, as well as buffer the volume variation during charge/discharge processes.