• 文献标题:   Visible active reduced graphene oxide loaded titania for photodecomposition of ciprofloxacin and its antibacterial activity
  • 文献类型:   Article
  • 作  者:   RAJA A, SELVAKUMAR K, RAJASEKARAN P, ARUNPANDIAN M, ASHOKKUMAR S, KAVIYARASU K, BAHADUR SA, SWAMINATHAN M
  • 作者关键词:   reduced graphene oxide, titania, ciprofloxacin, photocatalytic decomposition, antibacterial activity
  • 出版物名称:   COLLOIDS SURFACES APHYSICOCHEMICAL ENGINEERING ASPECTS
  • ISSN:   0927-7757 EI 1873-4359
  • 通讯作者地址:   Kalasalingam Acad Res Educ
  • 被引频次:   24
  • DOI:   10.1016/j.colsurfa.2018.12.024
  • 出版年:   2019

▎ 摘  要

The reduced Graphene Oxide based titanium dioxide (rGO-TiO2) nanocomposite was synthesized by a simple hydrothermal preparation and characterized by X-ray Diffraction Analysis (XRD), UV-vis absorption spectroscopy (UV), Fourier Transform Infrared spectroscopy (FT-IR), Thermogravimetric Analysis (TGA), Scanning Electron Microscopy (SEM) and Transmission Electron Microscopy (TEM). The XRD pattern of rGO-TiO2 indicates the presence of anatase TiO2 and average crystalline size of particles is 32 nm. The optical band gaps of TiO2, GO and rGO-TiO2 nanocomposite are 3.24 eV, 4.3 eV and 2.7 eV respectively. Comparison of efficiencies of three catalysts shows that ciprofloxacin degrades at a faster rate under visible light irradiation in the presence of rGO-TiO2 at 60 min than in presence of pure TiO2 and commercial TiO2-P25. Higher photocatalytic decom- position efficiency of rGO-TiO2 is explained by its reduced electron-hole recombination and visible light activity. The kinetics of photodecomposition reaction was analyzed. Antibacterial activity analysis of rGO-TiO2 nanoparticles reveals that it is more active against S. aureus than E. coli.