• 文献标题:   Surface-initiated photoinduced electron transfer ATRP and mussel-inspired chemistry: Surface engineering of graphene oxide for self-healing hydrogels
  • 文献类型:   Article
  • 作  者:   MA AY, JIANG CJ, LI MN, CAO LL, DENG ZH, BAI LJ, WANG WX, CHEN H, YANG HW, WEI DL
  • 作者关键词:   selfhealing hydrogel, nanocomposite, sipet atrp, musselinspired chemistry
  • 出版物名称:   REACTIVE FUNCTIONAL POLYMERS
  • ISSN:   1381-5148 EI 1873-166X
  • 通讯作者地址:   Ludong Univ
  • 被引频次:   2
  • DOI:   10.1016/j.reactfunctpolym.2020.104547
  • 出版年:   2020

▎ 摘  要

In this manuscript, self-healable nanocomposite hydrogels were successfully fabricated by combining surface-initiated photoinduced electron transfer-atom transfer radical polymerization (PET-ATRP) with mussel-inspired chemistry. Using these efficient and eco-friendly methods, poly(4-vinylpyridine) (P4VP) was initiated on the surface of graphene oxide (GO) via PET-ATRP with polydopamine (PDA) as the anchor and 10-phenylphe-nothiazine (PhPTZ) as organic photocatalyst, respectively. After in-situ polymerization of acrylic acid, self-healing nanocomposite hydrogels were successfully obtained, and they had excellent tensile strength (about 6.94 MPa), toughness (605%) performance as well as self-healing efficiency (94.9% after 8 h).