• 文献标题:   Reduced Graphene Oxide Reinforced Waterborne Soy Alkyd Nanocomposites: Formulation, Characterization, and Corrosion Inhibition Analysis
  • 文献类型:   Article
  • 作  者:   IRFAN M, BHAT SI, AHMAD S
  • 作者关键词:   waterborne, soy alkyd, rgo, nanocomposite, anticorrosive, phase angle
  • 出版物名称:   ACS SUSTAINABLE CHEMISTRY ENGINEERING
  • ISSN:   2168-0485
  • 通讯作者地址:   Jamia Millia Islamia
  • 被引频次:   5
  • DOI:   10.1021/acssuschemeng.8b03349
  • 出版年:   2018

▎ 摘  要

The waterborne soya alkyd (WSA) and its RGO dispersed nanocomposites (WSA-RGO) were synthesized via ex situ polymerization using a solvent-less green approach. The soya oil monoglyceride was used as precursor for waterborne alkyd. The synergistic effect of nanofillers and poly melamine coformaldehyde isobutylated solution modified organic matrix (WSA) on physicomechanical and corrosion inhibition of these coatings on finally polished carbon steel (CS) was investigated. Their physicochemical, physicomechanical, and thermal properties were analyzed using standard protocols. The electrochemical corrosion measurements of these coatings were performed using Potentiodynamic Polarization and Electrochemical Impedance Spectroscopy. The aforementioned studies revealed that the nanocomposite coatings exhibit promising corrosion protection performance which is evident from the i(corr) E-corr, impedance and phase angle values of coatings (i.e., i(corr) 7.736 x 10(-9) Acm(-2), E-corr -0.191 V, impedance similar to 10(7) Omega cm(2), and phase angle 86 degrees). These results suggest that the proposed waterborne nanocomposite coatings exhibit superior corrosion protection property than those of other such earlier reported systems.