• 文献标题:   Preparation and enhanced mechanical properties of non-covalently-functionalized graphene oxide/cellulose acetate nanocomposites
  • 文献类型:   Article
  • 作  者:   UDDIN ME, LAYEK RK, KIM HY, KIM NH, HUI D, LEE JH
  • 作者关键词:   nanostructure, polymermatrix composites pmcs, mechanical propertie, surface treatment
  • 出版物名称:   COMPOSITES PART BENGINEERING
  • ISSN:   1359-8368 EI 1879-1069
  • 通讯作者地址:   Chonbuk Natl Univ
  • 被引频次:   35
  • DOI:   10.1016/j.compositesb.2015.12.008
  • 出版年:   2016

▎ 摘  要

Sulfonated poly (ether-ether-ketone) (SPEEK) was selected as a surface modifying agent to prepare non-covalently functionalized reduced graphene oxide (NFrGO) followed by the development of NFrGO/cellulose acetate (CA) nanocomposite (NFrGO-CANC) through solution mixing. The formation of the nanocomposite was governed via the hydrogen bonding interactions among the -SO3H group of NFrGO and -OH/-C=0 groups of CA. NFrGO-CANC was characterized by field emission scanning electron microscopy, FT-IR, X-ray diffraction, thermogravimetric analysis, and differential scanning calorimetry analysis. The tensile strength of the NFrGO-CANC increased significantly with increasing NFrGO loading. The tensile strength and modulus of the NFrGO-CANC with 1.5 wt.% NFrGO were improved by similar to 102 and 143%, respectively, compared to those of pure CA. The onset degradation temperature and oxygen gas barrier properties of the NFrGO-CANC also were enhanced with increasing NFrGO loading up to 1.5 wt.% compared to those of pure CA film. (C) 2015 Elsevier Ltd. All rights reserved.